Data? data( K,T 2,300 4,500 8,700 ) plot(ln(K) vs. 1/T) m=slope b=intercept Delta_Ho=m*R Delta_So=b*R Ask examples: Show one value (72), but assign another (345.15) Temp of ($T_~345.15;72) Wrong answer gets alert (|): Right answer gets alert (!): When is q a state function?!Right, q is a state function when either pressure or volume is constant. When pressure is constant, q is DELTA_H; when volume is constant, q is DELTA_U. Quest examples: Options from data columns: ,['MOPT','$equation','What is the probability of drawing $drawwhat_ from the top of well-shuffled standard 52-card deck?'] Options from data columns as fill-in-the-blanks ,['MOPT','$effect','$cause_ the temperature of an endothermic reaction will result in _ in the value of the equilibrium constant.'] Options from list on question line ,['MOPT','vibrational,translational*,electronic','Rotational excitation generally requires more energy than _ excitation.'] Options from data columns, correct answer given ,['MOPT','$type:electronic','Which type of excitation is possible for all atoms and molecules in all three states of matter, solid, liquid, and gas?'] Options from data columns, more than one correct answer present--only present one ,['MOPT','$type:rotational,translational','Which type of excitation is not generally possible for solids?'] Options with answer determined by calculation ,['MOPT','endothermic,exothermic|[[(calcT(Equation,"Ho")>0?0:1)]]','Consider the Hess diagram shown below. Is this reaction endothermic or exothermic?[[hidden($eqn_);showHessH(Equation,5)]]'] Options with options and answer determined by calculation ,['MOPT','[[getSpeciesList(Equation)]]','Consider the Hess diagram shown below. Is this reaction endothermic or exothermic?[[hidden($eqn_);showHessH(Equation,5)]]'] Relative test, less is true ,['MREL','$type,$eorder,-1','Which of the following two types of energy level systems generally has the more closely spaced energy levels?'] Relative test, more is true ,['MREL','$type,$dorder,1','Which of the following two types of energy calculation involves the larger distance term?'] Relative test, from a column, with calculation ,['MREL','$column,[[whatevercalculation("$x_")]],1','Which of the following two types of energy calculation involves the larger distance terms, $mol1_ or $mol2_?'] True/False; false is correct ,['TF','0','Based on reduced mass, the rotational energy levels in HBr should be more closely spaced than those in I2.'] True/False; true is correct ,['TF','1','The reduced mass of a two-body system is always less than the smaller mass.'] True/False; with calculation ,['TF','[[calcDeltaU(Equation)>0?0:1]]','Consider the reaction shown below, [[hidden("$eqn2_")]] with DELTA_U=[[calcDeltaU(Equation)]] kJ. True or false: This reaction, if carried out in a calorimeter, will raise the temperature of the calorimeter.
$eqn2_
'] Calculation as JavaScript substitution ,['CALC','[[showMoleculeBDECalc("$mol_")]]','What is the bond dissociation energy of $mol_?'] Calculation with units indicated in brackets and roundoff indicated after @ ,['CALC','C = 1.00 [cal/g.K] * $ngram_ [g];Delta_T = [[$deg1_+$ddeg_]] - $deg1_ [oC or K];q_cal = C [cal/K] * Delta_T [K];q_kcal = q_cal * 1 [kcal] / 1000 [cal]@-2','The heat capacity of water is 1.00 cal/g/K. If a $ngram_ of water is heated from $deg1_ oC to [[$deg1_+$ddeg_]] oC, what is q in kilocalories? '] Calculation from equation on question line ,['CALC','n0=$n0_;n1=$n1_;n2=$n2_;n=n0+n1+n2;W=n!/(n0!n1!n2!)','Calculate W for the system shown below, with the indicated number of particles on each level.
$n2_
--------
$n1_
--------
$n0_
--------
'] Simplex calculation from standard equation; variables assigned from variable table ,['CALCS','BOLTZ:nj=1e10','A Boltzmann distribution at $T_ Kelvin has $ni_ particles in the ground state (energy 0 Joules). How many particles would have $dEij_ Joules of energy.']