To be presented at: 15th
BCCE, August 10, 1998, Waterloo, Ontario, Canada
Who is Watching? Developing a Clinical Chemistry
Dilemma and Assessment Tool for Role-Playing in Analytical Chemistry
Paul
T. Jackson and John P. Walters
St. Olaf College Chemistry Department
1520 St. Olaf Avenue
Northfield, MN 55057 USA
Contact: walters@stolaf.edu
or jackson@stolaf.edu
What is Role-Playing?
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Cooperative Learning Group
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Used in Training Professionals
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Counselors (social & religious)
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Physicians
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Teachers
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Used by Various Organizations
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Chemical abuse treatment centers
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Management
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Emergency personnel
Working Definition of Role-Playing:
Acting out deliberately exaggerated personality
or cultural stereotypes for the teaching of others and experiential learning.
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Role-Playing Group: A Company (Community)
The above figures are copyrighted to the American Chemical Society through
a three-part publication: Walters, J.P. Anal. Chem. 1991,
63, 977A, 1077A, 1179A. Used by permission.
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The role-playing experience is built around an understanding of a professional
analytical chemist's porfolio. We ask the students to accept that
this construct and responsibilities are those of an analytical chemist
and now learn analytical chemistry from within this definition. In
order to achieve this, we must divide responsibility, not labor.
Hence roles rotate and the manager is ultimately responsible for an experiement
- the planning, implementation, adaptations, results, group communication,
praise and criticism. See the above Analytical Chemistry papers
for additional information. Consequently the bottom line can be summed
up into two key sentences:
Good Grades Come from Good Results
Good Results Come from Good Management
Role-Playing Organization: Course Constructs
Analytical Chemistry - Junior level
Parallel Linked Group Activities
Instrumental Analysis - Senior level
Serial Linked Group Activities
ALL RESPONSIBILITY FOR ENSURING STUDENTS LEARN THE CONTENT
RESTS AT THE UPPER MANAGEMENT LEVEL.
Manager gets the Grade. The Company gets the
same grade as Manager.
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Key Elements of Role-Playing
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Interdependence Among Company Members
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Role Rotation
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Division of Responsibility
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Freedom Within a Mission
Key Elements of Collaborative Learning Groups
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Positive Interdependence
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Face-to-Face Promotive Interactions
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Individual Accountability - Personal Responsibility
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Collaborative Skills
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Group Processing
There is a direct link between what we consider as key elements in role-playing
and those emphasized by Johnson, Johnson and Smith. The only element
not included in typical CLG keys that we emphasize is "Freedom within a
mission". We define a mission for our company. We ask them
to solve a problem using the following resources: the company role-players
(no outsourcing), the company instrumentation, company computers, the library,
common chemicals, company supplies (glassware, etc.). Additionally,
we model what others have done in the past to stimulate thought.
The companys become very creative in developing and implementing a plan
to solve the problem. Often this results in two unique experiences
by the role-players: 1) they own their education - no one can take away
their creative solution and understanding of it; and 2) roles cross-teach
one another - that is they educate each other as to their roles impact
on the problem and provide assistance to others in the group.
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Pedagogical Objectives for Dilemma
As we started down our road to creating a capstone dilemma for the
role-playing experience we wanted it to come at the end of our department's
instrumental analysis course and contain sufficient flexibility for it
to last multiple weeks - a month would fit our January term. Our
objectives for the module follow:
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Incorporate Chromatography & Mass Spectrometry into Curriculum
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Emphasize Sample Preparation Prior to Analytical Measurements
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Develop an Appreciation for Power and Limitations of Commercial
Software
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Add Current Literature into Laboratory
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Assessment Tool for Teaching Method
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Social Sensitivity & Ethics: an Essential Part of the
Analytical Chemist's Professional Portfolio
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Selection of a Chemical System
Our choice of chemical system got us started. We wanted a system
with the features listed below. However, our friends in the Minnesota
Bureau of Criminal Apprehension brought to our attention some of the legal
and ethical challenges to us as educators. We do not want to send
a message that "drugs are cool" or show our students "how to beat a GC-MS
confirmatory test". Thus, we decided not to pursue the illicit drugs
but focus on a remarkable similar class of over-the-counter medications
that have been abused - ephedrines.
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Societal Context or Social Relevance
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Amenable to Derivatization
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Useful and Interesting Chemistry
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Legal and Ethical Ramifications
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Reasonable Quantities Available
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Experimental Design
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Laboratory Certification as the Dilemma Base
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EI Mass Spectra Similarity - Unique Analytical Problem
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Methamphetamine/Ephedrine
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Amphetamine/Phenylpropanolamine
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Synthetic Urine Sample Provided
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Preseparation & Preconcentration
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SPE 3M C8 EmporeTM
Cartridges
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Derivatization vs Preconcentration Management Decision
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Trifluoroacetic Anhydride
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Acetic Anhydride
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Propylchloroformate
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Quantitative Measurement with an Internal Standard
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Standard Addition
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Standard Curve
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An Example of Role Responsibilities Within this Module
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Ephedrine Analysis Protocols
Chain of Custody Procedures
Mgmt Reports on Method
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Operates GC-MS System
SPE System Configuration
pH Meter Operation
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GC-MS System Software
Database Searching
Data Telemetry & Analysis
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Derivatization Chemistry
Internal Standards
Specific Gravity Determination
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Experimental Data: GC-MS Analysis of Ephedrines
and Internal Standard Candidates
Propylchloroformate Aqueous Derivatization
of Amines (Labeled left to right)
SPE: 1 mL C8 Empore Cartridge
Injection: 1 mL splitless
(0.67 min), 220 °C
Column: Rtx-35, 30 m x 0.25 mm x 0.25 mm
film
Oven: 50 °C @ 2 min; 70 °C/min to 130 °C;
8 °C/min to 250 °C; 250 °C @ 3 min
Solutes: BMPEA = b-methylphenethylamine
NBBA = N-butylbenzylamine
THIQ = 1,2,3,4-tetrahydroisoquinoline
(1R,2S)-(-)-Ephedrine Standard Curve
Propyl chloroformate derivative
Internal Standard: N-butylbenzylamine
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Cost of Doing Business
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Shared GC-MS Instrument - Multiple Curricula
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Dual Injection Ports, Switching Valve
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Users Manual
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Sample Preparation Equipment
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Limited Library Facilities
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Compose Database
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Journal Articles Available
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Sustainability
Feedback and Observations Using Role-Playing
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STUDENT OWNERSHIP of Course and Materials
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Students Give Rewards for Good Work
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Students Address Communication Problems: Stress & Decision
Making
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Companies Exchange Information
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Companies Forge Unique Approach to Problem Solving
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Four Roles per Company Work Best
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Rotation is Critical
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Company Organization Provides Immediate Activity Forum
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Class-Lab Link Induction Period - it takes students a little
time to adjust!
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Professional Costs
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Leveraged Professional Risk - Tenure
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Creative Professional Activity
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What is it?
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How is it done?
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What is its net worth?
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Funding
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Technology
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Infrastructure
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Disseminating Information
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Students
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Colleagues
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Administrators
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Management and Role-Playing Resources
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Roberts, B.B.; Thorsheim, H.I. Empowering Leadership:
A Brief Introduction, Lutheran Brotherhood Foundation, 1987.
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Pascale, R.T. Managing on the Edge, Simon and Schuster:
New York, 1990.
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Blanchard, K.; Johnson, S. The One Minute Manager,
Berkely Books: New York, 1986.
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Silverstien, S. The Giving Tree, Harper and Row: New
York, 1964.
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Peck, M.S. The Different Drum: Community Making and Peace,
Simon and Schuster: New York, 1987.
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Walters, J.P. "Role-Playing in Analytical Chemistry" Anal.
Chem. 1991, 63, 977A, 1077A, 1179A.
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Jackson, P.T. "Essay
on Role-Playing in Analytical Chemistry"
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Summary and Acknowledgements
Role-Playing is one of many Cooperative Learning
Constructs
Role-Playing is an Effective Means of Teaching Chemistry
Role-Playing Engages Both Student and Instructor
Role-Playing Carries Professional Costs
Funding:
Camille & Henry Dreyfus Foundation
St. Olaf College
Consultants:
Dr. Larry Bowers, IUPUI
Ms. Betty Rogers, MNBCA
Mr. Glenn Hardin, MNBCA
The People that Help Make it Happen:
The Students of St. Olaf College
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Last Modified: 14 August 1998
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