TETRAHEDRAL (AX4)

This is an example of a tetrahedral molecule. These molecules consist of 4 atoms surrounding a central atom, creating four faces.

Tetrahedral molecules are under the category, AX4 and have sp3 sigma hybridization. Methane, or CH4, is a good example of a tetrahedral molecule. It has four C-H bonds with no lone pairs on any atom. It is described as a perfect tetrahedron because all of its angles are 109.45 degrees and the bonds are all 1.09 Angstroms. Carbon tetrafluoride, or CF4 is also a perfect tetrahedral molecule. It has four C-F bonds, with C as the central atom. The four F atoms have 3 lone pairs on each. The length of the F-C bonds are all 1.32 Angstroms forming equal 109.45 degree angles. Sulfuric acid or H2SO4 is also a tetrahedral molecule. Sulfuric acid has sulfur as its central atom, and has two O atoms, and two OH groups surrounding it. The HO-S-OH angle is smaller than the O=S=O angle. This is because the double bonds between O and S create a shorter distance and the OH groups are repelled by the O atoms coming closer. As a result, the O=S=O angle is larger than the HO-S-OH angle.

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